Characteristics of the Structural State of Bismuth Ions in Bismuth-Borate Glasses

被引：4
|
作者：
Bobkova, N. M. [1 ]
机构：
[1] Belarusian State Technol Univ, Minsk, BELARUS
来源：
GLASS AND CERAMICS | 2019年 / 75卷 / 9-10期
关键词：
lead-free low-melting glasses; properties of bismuth-borate glasses; structural role of Bi ions; structure of bismuth-borate glasses;
D O I：
10.1007/s10717-019-00090-w
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
The properties and graphical plots of the properties of bismuth-borate glasses in a wide range of compositions20 to 80 mol.% Bi2O3 are presented. In multi-bismuth glasses both the boron and bismuth ions are found in two coordination states: B3+, B4+ and Bi3+, Bi6+. The [BiO3] groups play the role of a conventional glass former but manifest weakly in the IR spectra.
引用
收藏
页码：383 / 386
页数：4
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