Pitting corrosion behaviour of austenitic stainless steels with Cu and Sn additions

被引:83
作者
Pardo, A. [1 ]
Merino, M. C. [1 ]
Carboneras, M. [1 ]
Coy, A. E. [1 ]
Arrabal, R. [1 ]
机构
[1] Univ Complutense Madrid, Fac Quim, Dept Ciencia Mat, E-28040 Madrid, Spain
关键词
stainless steel; copper; tin; polarization; pitting corrosion;
D O I
10.1016/j.corsci.2006.06.004
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The influence of Cu and Sn on the pitting corrosion resistance of AISI 304 and 316 stainless steels in chloride-containing media has been investigated. The corrosion behaviour was evaluated by cyclic polarization, potentiostatic CPT measurements and electrochemical impedance spectroscopy in 3.5 wt% NaCl. The corrosion resistance was also studied in FeCl3 under Standard ASTM G-48. According to the results, Cu addition favours pit nucleation but inhibits its growth, whereas Sn exerts the opposite effect, favouring pit growth and inhibiting its nucleation. Studies by SEM, X-ray mapping and EDS analysis showed Cu-, Cl- and O-rich corrosion products that reduce the extent of corrosion damage. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:510 / 525
页数:16
相关论文
共 34 条
[1]  
ABO H, 1974, BOSHOKU GIJUTSU, V23, P303
[2]  
Botella J., 1998, REV METAL MADRID, V34, P12
[3]  
BRUBAKER SK, 1994, METALS HDB, V13, P1148
[4]  
BUCK DM, 1921, T AM ELECTROCHEM SOC, V39, P109
[5]  
Fritz JD, 2001, ADV MATER PROCESS, V159, P36
[6]   The influence of copper addition on the formability of AISI 304 stainless steel [J].
Gonzalez, BM ;
Castro, CSB ;
Buono, VTL ;
Vilela, JMC ;
Andrade, MS ;
Moraes, JMD ;
Mantel, MJ .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2003, 343 (1-2) :51-56
[7]  
HEGER JJ, 1982, ADV TECHNOLOGY STAIN
[8]  
HEINKE G, 1996, P INT C STAINL STEEL, P12
[9]   ACCUMULATION OF COPPER LAYER ON A SURFACE IN THE ANODIC POLARIZATION OF STAINLESS-STEEL CONTAINING CU AT DIFFERENT TEMPERATURES [J].
HERMAS, AA ;
OGURA, K ;
ADACHI, T .
ELECTROCHIMICA ACTA, 1995, 40 (07) :837-844
[10]   EFFECTS OF ALLOYING ADDITIONS ON CORROSION AND PASSIVATION BEHAVIORS OF TYPE-304 STAINLESS-STEEL [J].
HERMAS, AA ;
OGURA, K ;
TAKAGI, S ;
ADACHI, T .
CORROSION, 1995, 51 (01) :3-10