HETEROGENEOUS CATALYSIS Confined microenvironment for catalysis control

被引：89

作者：

Fu, Qiang ^{[1
]}

Bao, Xinhe ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian, Peoples R China

来源：

NATURE CATALYSIS | 2019年 / 2卷 / 10期

关键词：

D O I：

10.1038/s41929-019-0354-z

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The design of heterogeneous catalysts with tunable activity and selectivity constitutes a remarkable challenge. Now, a synthetic approach towards producing nanocrystals encapsulated within polymer layers has been developed, unravelling the principles to achieve control of transition state and product diffusion using CO oxidation as a case study.

引用

页码：834 / 836

页数：3

共 9 条

[1] Reactions at surfaces: From atoms to complexity (Nobel lecture) [J].

Ertl, Gerhard .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (19) :3524-3535

[2] Confined catalysis under two-dimensional materials [J].

Li, Haobo ;

Xiao, Jianping ;

Fu, Qiang ;

Bao, Xinhe .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2017, 114 (23) :5930-5934

[3] Confinement Effects in Catalysis Using Well-Defined Materials and Cages [J].

Mouarrawis, Valentinos ;

Plessius, Raoul ;

van der Vlugt, Jarl Ivar ;

Reek, Joost N. H. .

FRONTIERS IN CHEMISTRY, 2018, 6

[4] The nature of the active site in heterogeneous metal catalysis [J].

Norskov, Jens K. ;

Bligaard, Thomas ;

Hvolbaek, Britt ;

Abild-Pedersen, Frank ;

Chorkendorff, Ib ;

Christensen, Claus H. .

CHEMICAL SOCIETY REVIEWS, 2008, 37 (10) :2163-2171

[5] Transition state and product diffusion control by polymer-nanocrystal hybrid catalysts [J].

Riscoe, Andrew R. ;

Wrasman, Cody J. ;

Herzing, Andrew A. ;

Hoffman, Adam S. ;

Menon, Aditya ;

Boubnov, Alexey ;

Vargas, Maria ;

Bare, Simon R. ;

Cargnello, Matteo .

NATURE CATALYSIS, 2019, 2 (10) :852-863

[6] The confinement effect in zeolites [J].

Sastre, G. ;

Corma, A. .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2009, 305 (1-2) :3-7

[7] A theory of the catalytic surface [J].

Taylor, HS .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-CONTAINING PAPERS OF A MATHEMATICAL AND PHYSICAL CHARACTER, 1925, 108 (745) :105-111

[8] Catalysis: principles, progress, prospects [J].

Thomas, JM ;

Williams, JP .

PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 2005, 363 (1829) :765-791

[9] Toward Fundamentals of Confined Catalysis in Carbon Nanotubes [J].

Xiao, Jianping ;

Pan, Xiulian ;

Guo, Shujing ;

Ren, Pengju ;

Bao, Xinhe .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (01) :477-482

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