Synthesis, characterization, and crystal structures of various energetic urotropinium salts with azide, nitrate, dinitramide and azotetrazolate counter ions

被引：0

作者：

Ang, HG

Fraenk, W

Karaghiosoff, K

Klapötke, TM

Nöth, H

Sprott, J

Suter, M

Vogt, M

Warchhold, M

机构：

[1] Univ Munich, Dept Chem, D-81377 Munich, Germany

[2] Natl Univ Singapore, Dept Chem, Singapore 117548, Singapore

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2002年 / 628卷 / 13期

关键词：

urotropinium; N-methylurotropinium; azides; nitrates; dinitramides; azotetrazolate salts; crystal structure; NMR spectroscopy (multinuclear); vibrational spectroscopy;

D O I：

10.1002/1521-3749(200213)628:13<2901::AID-ZAAC2901>3.0.CO;2-K

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Urotropinium nitrate, N-methylurotropinium azide, dinitramide and azotetrazolate salts have been prepared and fully characterized by analytical and spectoscopic (H-1, C-13, N-14 NMR, IR, Raman) methods. The structures of all four compounds have been determined using X-ray diffraction techniques and represent new examples of the class of high energy density materials (HEDMs).

引用

页码：2901 / 2906

页数：6

共 17 条

[1] The dinitramide anion, N(NO2)(2)(-) [J].