Iron(II) complexes bearing tridentate PNP pincer-type ligands as catalysts for the selective formation of 3-hydroxyacrylates from aromatic aldehydes and ethyldiazoacetate

被引：85

作者：

Benito-Garagorri, David

Wiedermann, Julia

Pollak, Martin

Mereiter, Kurt

Kirchner, Karl

机构：

[1] Vienna Univ Technol, Inst Appl Synth Chem, A-1060 Vienna, Austria

[2] Vienna Univ Technol, Inst Chem Technol & Analyt, A-1060 Vienna, Austria

来源：

ORGANOMETALLICS | 2007年 / 26卷 / 01期

关键词：

D O I：

10.1021/om060802o

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Several new iron(II) complexes of the types [Fe(PNP)(CO)(CH3CN)(2)](2+), [Fe(PNP)(CO)(2)Br](+), and Fe(PNP)Cl-2 containing tridentate PNP pincer-type ligands have been prepared and characterized. Some of them turned out to be efficient catalysts for the coupling of aromatic aldehydes with ethyldiazoacetate (EDA) to give 3-hydroxyacrylates. These reactions are highly chemoselective, proceed under mild conditions, exhibit good scope, and circumvent the need of slow addition of EDA at low temperature.

引用

页码：217 / 222

页数：6

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