Base catalysed hydrolysis of aminecobalt(III) complexes: From the beginnings to the present

被引：26
作者：
Jackson, WG [1 ]
机构：
[1] Univ New S Wales, Australian Def Force Acad, Sch Chem, Univ Coll, Canberra, ACT 2600, Australia
来源：
INORGANIC REACTION MECHANISMS | 2002年 / 4卷 / 1-2期
关键词：
base hydrolysis; cobalt(III); mechanisms; intermediates;
D O I：
10.1080/102866202100002518
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This review examines the base catalysed hydrolysis process for cobalt(III) complexes. An overview of the reaction from its initial development to the present day is presented. The various mechanisms developed over the years, including S N 1CB, ion-pair, pseudo-base (covalent hydration), pseudo-aminate and E2 mechanisms, are presented and examined. Electronic, bulk steric, leaving group and solvent effects are covered. The question of and evidence for reduced coordination number intermediates is addressed in some detail. The review places an emphasis on current directions of research.
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页码：1 / 30
页数：30
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