Specific alkylidene coupling of the labile diruthenium bridging methylene complex [(eta-C5H5)(2)Ru-2(mu-CH2)(CO)(2)(MeCN)] with diazoalkanes (N-2=CR(2)) giving alkenic products

被引：12

作者：

Akita, M ^{[1
]}

Hua, RM ^{[1
]}

Knox, SAR ^{[1
]}

MoroOka, Y ^{[1
]}

Nakanishi, S ^{[1
]}

Yates, MI ^{[1
]}

机构：

[1] UNIV BRISTOL,SCH CHEM,BRISTOL BS8 1TS,AVON,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 01期

关键词：

D O I：

10.1039/a606525b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of the labile diruthenium bridging methylene complex [(eta-C5H5)(2)Ru-2(mu-CH2)(mu-CO)(CO)(MeCN)] with diazoalkanes (N-2=CR(1)R(2)) results in specific C-C coupling to give alkenic products, i.e. the bridging alkenyl complex [(eta-C5H5)(2)Ru-2(mu-CH-CHR(1))(mu-H)(CO)(2)] (R(2) = H) or alkene CH2=CR(1)R(2) (R(1), R(2) not equal H).

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页码：51 / 52

页数：2

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