Shape-controlled synthesis and lithium-storage study of metal-organic frameworks Zn4O(1,3,5-benzenetribenzoate)2

被引：314

作者：

Li, Xiaoxia ^{[1
]}

Cheng, Fangyi ^{[1
]}

Zhang, Shuna ^{[1
]}

Chen, Jun ^{[1
]}

机构：

[1] Nankai Univ, Inst New Energy Mat Chem, Tianjin 300071, Peoples R China

来源：

JOURNAL OF POWER SOURCES | 2006年 / 160卷 / 01期

关键词：

MOF-177; lithium batteries; shape-control synthesis;

D O I：

10.1016/j.jpowsour.2006.01.015

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Polycrystalline metal-organic frameworks Zn4O(1,3,5-benzenetribenzoate)(2) (named as MOF-177) with different morphologies have been controlled synthesized through a solvothermal route. MOF-177 electrodes for lithium storage exhibit a relatively high irreversible capacity in the first discharge process and a much lower reversible discharge-charge capacity in the following electrochemical cycles. The performance of MOF-177 is found not impressive for application in reversible lithium storage. A preliminary reaction mechanism on the basis of transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS) is proposed to understand the chemical behaviors of the electrode. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：542 / 547

页数：6

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