Applications of Diphosphines in Radical Reactions

被引：13

作者：

Kawaguchi, Shin-ichi ^{[1
]}

Ogawa, Akiya ^{[2
]}

机构：

[1] Saga Univ, Fac Agr, Educ & Res Agr Innovat, 152-1 Shonan Cho Karatsu, Saga 8470021, Japan

[2] Osaka Prefecture Univ, Grad Sch Engn, Dept Appl Chem, Naka Ku, 1-1 Gakuen Cho, Sakai, Osaka 5998531, Japan

来源：

ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2019年 / 8卷 / 08期

关键词：

phosphanes; radical reactions; photochemistry; radicals; P-PERFLUOROALKYLATED PHOSPHINES; PHOTO-INITIATED ADDITION; HOMOLYTIC SUBSTITUTION; PHOSPHORUS; TETRAPHENYLDIPHOSPHINE; ALKYNES; CONDENSATION; DISULFIDES; DISELENIDE; ACCESS;

D O I：

10.1002/ajoc.201900339

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Recently, the importance of organophosphorus compounds in organic chemistry has increased. Diphosphines are an attractive source of phosphorus containing two phosphorus groups, which can theoretically be introduced into a carbon framework with high atom economy. There are several diphosphine derivatives, which are closely related to diphosphines, but their reactivities are completely different. In this Minireview, we describe various phosphination reactions with diphosphines and their derivatives under radical conditions.

引用

页码：1164 / 1173

页数：10

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