Key Considerations for Sensing FeII and FeIII in Aqueous Media

被引：8
作者：
Burdette, Shawn C. [1 ]
机构：
[1] Worcester Polytech Inst, Dept Chem & Biochem, Worcester, MA 01609 USA
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2015年 / 35期
关键词：
Fluorescent probes; Sensors; Iron; SENSOR;
D O I：
10.1002/ejic.201500566
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Recently Ghosh et al. reported on the fluorescent response of commercially available N-(2-aminoethyl) naphthalen-1-amine toward Fe-II, Fe-III, and Hg-II (K. Ghosh, S. Rathi, P. Gupta, P. Vashisth, V. Pruthi, Eur. J. Inorg. Chem. 2015, 311). The authors conclude that metal binding to the diamine chelator leads to chelation-induced quenching; however, the experimental protocols are incompatible with the aqueous chemistry of Fe-III, which precludes this interpretation of the data.
引用
收藏
页码：5728 / 5729
页数：2
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