Stereoselective catalytic hydrogenation of sorbic acid and sorbic alcohol with new Cp*Ru complexes

被引：41
|
作者：
Steines, S
Englert, U
Driessen-Hölscher, B
机构：
[1] Rhein Westfal TH Aachen, Inst Tech Chem & Petrolchem, D-52056 Aachen, Germany
[2] Rhein Westfal TH Aachen, Inst Anorgan Chem, D-52056 Aachen, Germany
来源：
CHEMICAL COMMUNICATIONS | 2000年 / 03期
关键词：
D O I：
10.1039/a909355i
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The new Cp*Ru complexes [Cp*Ru(eta(4)-MeCH=CHCH=CHCO2H)]X-+(-) (X- = CF3SO3- or [B{C6H3(CF3)(2)-3,5}(4)](-)) are very effective catalysts for the hydrogenation of sorbic acid to cis-hex-3-enoic acid and of sorbic alcohol to cis-hex-3-en-1-ol (leaf alcohol) under mild conditions in liquid two-phase systems.
引用
收藏
页码：217 / 218
页数：2
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