Crystal Structure of cis-Bis(2,2′-bipyridyl)bis(trifluoromethanesulfonato)cobalt(II)

被引：1

作者：

Toyama, Mari ^{[1
]}

Yamamoto, Yu ^{[1
]}

机构：

[1] Konan Univ, Fac Sci & Engn, Dept Chem Funct Mol, Higashinada Ku, 8-9-1 Okamoto, Kobe, Hyogo 6588501, Japan

来源：

X-RAY STRUCTURE ANALYSIS ONLINE | 2019年 / 35卷

关键词：

COMPLEXES;

D O I：

10.2116/xraystruct.35.21

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

A cobalt(II) complex with two 2,2'-bipyridine (bpy) and two trifluoromethanesulfonato (OTf-) ligands, cis-[Co-II(OTf)(2)(bpy)(2)], was prepared, and the crystal structure at 173 K was elucidated by the single-crystal X-ray diffraction method. The complex crystallized in the monoclinic space group C2/c with a = 9.90587(16), b = 14.2978(2), c = 18.6626(3)angstrom, alpha = 90, beta = 101.6670(17), gamma = 90 degrees, Z = 4, V = 2588.61(7)angstrom(3). The R1 and wR2 values were 0.0397 and 0.1016, respectively, for 2377 reflections.

引用

页码：21 / 23

页数：3

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