New Revolution in Biaryl Synthesis: Transition Metal-Free C-C Bond Formation Promoted by the Mixture of 2-Mercaptoethanol/KOH/DMSO

被引：4
|
作者：
Ghorbani-Choghamarani, Arash [1 ]
Taherinia, Zahra [1 ]
机构：
[1] Ilam Univ, Fac Sci, Dept Chem, POB 69315516, Ilam, Iran
来源：
CHEMISTRYSELECT | 2019年 / 4卷 / 16期
关键词：
C-C coupling; DMSO; KOH; 2-Mercaptoethanol; Metal-free; CROSS-COUPLING REACTIONS; ARYLATION; BENZENE; COMPLEXES; ELECTRON; WATER;
D O I：
10.1002/slct.201900801
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This research project introduced a novel transition metal-free C C coupling reaction that is believed to be a new revolution in Suzuki type reactions. Carbon-carbon bond formation can be promoted by a mixture of 2-mercaptoethanol/ KOH/ DMSO without the aid of any transition metals. It has been suggested that this reaction proceeds through radical species, hence the electron transfer route is suggested for the operation during the oxidation of 2-mercaptoethanol in DMSO.
引用
收藏
页码：4735 / 4738
页数：4
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