A highly active PtCu3 intermetallic core-shell, multilayered Pt-skin, carbon embedded electrocatalyst produced by a scale-up sol-gel synthesis

被引：77

作者：

Bele, M. ^{[1
]}

Jovanovic, P. ^{[1
]}

Pavlisic, A. ^{[1
]}

Jozinovic, B. ^{[1
]}

Zorko, M. ^{[1
]}

Recnik, A. ^{[2
]}

Chernyshova, E. ^{[1
]}

Hocevar, S. ^{[3
]}

Hodnik, N. ^{[3
]}

Gaberscek, M. ^{[1
]}

机构：

[1] Natl Inst Chem, Lab Mat Chem, Ljubljana 1000, Slovenia

[2] Jozef Stefan Inst, Dept Nanostruct Mat, Ljubljana 1000, Slovenia

[3] Natl Inst Chem, Lab Catalysis & Chem React Engn, Ljubljana 1000, Slovenia

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 86期

关键词：

OXYGEN REDUCTION REACTION; METHANOL OXIDATION REACTION; FUEL-CELL CATALYSTS; NANOPARTICLES; DEGRADATION; STABILITY; PLATINUM;

D O I：

10.1039/c4cc05637j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We present a novel, scaled-up sol-gel synthesis which enables one to produce 20 g batches of highly active and stable carbon supported PtCu3 nanoparticles as cathode materials for low temperature fuel cell application. We confirm the presence of an ordered intermetallic phase underneath a multilayered Pt-skin together with firm embedment of nanoparticles in the carbon matrix.

引用

收藏

页码：13124 / 13126

页数：3

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