Mechanisms involved in the platinization of sol-gel-derived TiO2 thin films

被引:14
作者
Riassetto, D. [1 ]
Holtzinger, C. [1 ]
Messaoud, M. [1 ]
Briche, S. [1 ]
Berthome, G. [2 ]
Roussel, F. [3 ]
Rapenne, L. [1 ]
Langlet, M. [1 ]
机构
[1] Grenoble Inst Technol, LMGP, F-38016 Grenoble 1, France
[2] Domaine Univ, Grenoble Inst Technol, SIMAP, F-38402 St Martin Dheres, France
[3] Domaine Univ, Grenoble Inst Technol, CMTC, F-38402 St Martin Dheres, France
关键词
Photocatalysis; Photolysis; TiO2; Sol-gel; Thin film; Platinum; PHOTOCATALYTIC ACTIVITY; PLATINUM NANOPARTICLES; TITANIUM-DIOXIDE; PT/TIO2; REDUCTION; OXIDATION; DEPOSITION; COMPLEXES; ELECTRONS; SURFACES;
D O I
10.1016/j.jphotochem.2008.11.023
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Sol-gel TiO2 thin films have been loaded with platinum nano-particles via their immersion within a pt(4+) precursor liquid solution exposed to UV light. Mechanisms involved in the photo-induced formation of platinum particles have been studied by UV/visible spectroscopy, X-ray photoelectron spectroscopy, energy dispersive X-ray analysis, scanning electron microscopy, and transmission electron microscopy. According to studied mechanisms, it is shown that the amount, size, and structural state of photo-generated platinum particles dispersed at a solid surface can flexibly be monitored. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:214 / 220
页数:7
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