Synthesis and Two-Photon Spectrum of a Bis(Porphyrin)-Substituted Squaraine

被引：80
作者：
Odom, Susan A. [1 ,2 ]
Webster, Scott [3 ]
Padilha, Lazaro A. [3 ]
Peceli, Davorin [3 ]
Hu, Honghua [3 ]
Nootz, Gero [3 ]
Chung, Sung-Jae [1 ,2 ]
Ohira, Shino [1 ,2 ]
Matichak, Jonathan D. [1 ,2 ]
Przhonska, Olga V. [4 ]
Kachkovski, Alexei D. [5 ]
Barlow, Stephen [1 ,2 ]
Bredas, Jean-Luc [1 ,2 ]
Anderson, Harry L. [6 ]
Hagan, David J. [3 ]
Van Stryland, Eric W. [3 ]
Marder, Seth R. [1 ,2 ]
机构：
[1] Georgia Inst Technol, Sch Chem & Biochem, Atlanta, GA 30332 USA
[2] Georgia Inst Technol, Ctr Organ Photon & Elect, Atlanta, GA 30332 USA
[3] Univ Cent Florida, Coll Opt & Photon, CREOL, Orlando, FL 32826 USA
[4] Natl Acad Sci Ukraine, Inst Phys, UA-03028 Kiev, Ukraine
[5] Natl Acad Sci Ukraine, Inst Organ Chem, UA-03094 Kiev, Ukraine
[6] Univ Oxford, Dept Chem, Oxford OX1 3TA, England
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 22期
基金：
美国国家科学基金会;
关键词：
CONJUGATED PORPHYRIN DIMERS; ABSORPTION CROSS-SECTIONS; CHROMOPHORES; ENHANCEMENT; OLIGOMERS; MOLECULES; MODEL;
D O I：
10.1021/ja901244e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A chromophore in which zinc porphyrin donors are linked through their meso positions by ethynyl bridges to a bis(indolinylidenemethyl) squaraine core has been synthesized using Sonogashira coupling. The chromophore exhibits a two-photon absorption spectrum characterized by a peak cross section of 11000 GM and, more unusually, also exhibits a large cross section of >780 GM over a photon-wavelength window 750 nm in width.
引用
收藏
页码：7510 / +
页数：4
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