Spectral-luminescent properties of Eu3+ ions in inorganic D2O and POCl3-SnCl4 solvents

被引：3
作者：
Seregina, EA [1 ]
Seregin, AA [1 ]
机构：
[1] Obninsk Phys & Power Engn Inst, Obninsk 249020, Kaluga Oblast, Russia
来源：
OPTICS AND SPECTROSCOPY | 2002年 / 92卷 / 05期
基金：
俄罗斯基础研究基金会;
关键词：
ACKNOWLEDGMENTS We thank G.V. Tikhonov for preparing D2O–Eu3+ and POCl3–SnCl4–Eu3+ solutions. We are also grateful to P.P. D’yachenko for reading the manuscript and for helpful comments. This study was supported by the Russian Foundation for Basic Research; project no. 01-02-16551;
D O I：
10.1134/1.1481128
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
Absorption and luminescence spectra of Eu3+ ions in D2O and POCl3-SnCl4 inorganic solvents were measured. Oscillator strengths and spontaneous radiation transition probabilities for the most intense electron transitions in Eu3+ were calculated. Judd-Ofelt parameters, the radiative lifetime of the D-5(o) metastable level of Eu3+ in D2O-Eu3+ and POCl-SnCl4-Eu3+ solutions, and matrix elements for radiative transitions from the D-5(o) level were determined. The luminescence lifetime of the D-5(o) level of Eu3+ in these solutions was measured. The photoluminescence quantum yield for transitions from the D-5(o) level of Eu3+ in D2O-Eu3+ and POCl3-SnCl4-Eu3+ solutions was found to be 0.32 and 0.88, respectively. (C) 2002 MAIK "Nauka/Interperiodica".
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页码：664 / 669
页数：6
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