The thermal and light induced spin transition in [FeL2](BF4)2 (L=2,6-dipyrazol-1-yl-4-hydroxymethylpyridine)

被引：44
作者：
Money, VA
Elhaïk, J
Halcrow, MA
Howard, JAK
机构：
[1] Univ Durham, Dept Chem, Durham DH1 3LE, England
[2] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England
来源：
DALTON TRANSACTIONS | 2004年 / 10期
关键词：
D O I：
10.1039/b401155d
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This communication presents the crystal structures of the high spin state at 300 K, the low spin state at 30 K and the metastable high spin state after irradiation at 30 K and an estimate of the critical LIESST temperature of [FeL2]( BF4)(2) which is shown to undergo a spin transition at 271 K.
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收藏
页码：1516 / 1518
页数：3
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