Ruthenium on chitosan: a recyclable heterogeneous catalyst for aqueous hydration of nitriles to amides

被引：105
作者：
Baig, R. B. Nasir [1 ]
Nadagouda, Mallikarjuna N. [1 ]
Varma, Rajender S. [1 ]
机构：
[1] US EPA, Sustainable Technol Div, Natl Risk Management Res Lab, Cincinnati, OH 45268 USA
来源：
GREEN CHEMISTRY | 2014年 / 16卷 / 04期
关键词：
ORGANIC-SYNTHESIS; NATURAL PHOSPHATE; AMINO-ACIDS; HYDROXYAPATITE; WATER; CYCLOADDITION; HYDROLYSIS; ADSORPTION; BIOPOLYMER; COMPLEXES;
D O I：
10.1039/c3gc42004c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Ruthenium has been immobilized over chitosan by simply stirring an aqueous suspension of chitosan in water with ruthenium chloride, and has been utilized for the oxidation of nitriles to amides; the hydration of nitriles occurs in high yield and excellent selectivity, which proceeds exclusively in aqueous medium under neutral conditions.
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收藏
页码：2122 / 2127
页数：6
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