A facile and selective procedure for transesterification of β-keto esters promoted by yttria-zirconia based Lewis acid catalyst

被引:0
作者
Kumar, P [1 ]
Pandey, RK [1 ]
机构
[1] Natl Chem Lab, Div Organ Chem Technol, Poona 411008, Maharashtra, India
关键词
transesterification; beta-keto esters; alcohols; yttria-zirconia based Lewis acid; heterogeneous catalysis;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An yttria-zirconia based strong Lewis acid efficiently catalyses the transesterification of beta-keto esters under environmentally safe, heterogeneous reaction conditions with high selectivity and in good to excellent yields.
引用
收藏
页码:251 / 253
页数:3
相关论文
共 26 条
[1]   Simple and high yielding syntheses of β-ketoesters catalysed by zeolites [J].
Balaji, BS ;
Chanda, BM .
TETRAHEDRON, 1998, 54 (43) :13237-13252
[2]   A facile and selective synthesis of beta-keto esters via zeolite catalysed transesterification [J].
Balaji, BS ;
Sasidharan, M ;
Kumar, R ;
Chanda, B .
CHEMICAL COMMUNICATIONS, 1996, (06) :707-708
[3]   ANTICONVULSANTS .5. ESTERS OF GAMMA-DIETHYLAMINO-ALPHA-PHENYLBUTYRIC ACID [J].
BILLMAN, JH ;
SMITH, WT ;
RENDALL, JL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1947, 69 (08) :2058-2059
[4]  
BLOSSEY EC, 1973, TETRAHEDRON LETT, P1823
[5]   KETEN INTERMEDIATES IN UNCATALYSED ALCOHOLYSIS OF BETA-KETO-ESTERS AND RELATED COMPOUNDS [J].
CAMPBELL, DS ;
LAWRIE, CW .
JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1971, (07) :355-&
[6]   Addition of alpha beta-unsaturated alcohols to the active methylene group Part I The action of ethyl acetoacetate on linalool and geraniol [J].
Carroll, MF .
JOURNAL OF THE CHEMICAL SOCIETY, 1940, :704-706
[7]   Use of solid superacid (Sulphated SnO2) as efficient catalyst in facile transesterification of ketoesters [J].
Chavan, SP ;
Zubaidha, PK ;
Dantale, SW ;
Keshavaraja, A ;
Ramaswamy, AV ;
Ravindranathan, T .
TETRAHEDRON LETTERS, 1996, 37 (02) :233-236
[8]   Enantioselective synthesis of (-)-curcumanolide A using enzymatic transesterification of meso-spirodiol [J].
Fujita, T ;
Tanaka, M ;
Norimine, Y ;
Suemune, H ;
Sakai, K .
JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (12) :3824-3830
[9]  
Haken J.K., 1963, J APPL CHEM, V13, P168
[10]  
Kesharavaja A., 1999, Process for the c-c bond forming reaction using solid acid catalyst, Patent No. 5932752