Controlled/"living" polymerization of sulfobetaine monomers directly in aqueous media via RAFT

被引：115
作者：
Donovan, MS
Sumerlin, BS
Lowe, AB
McCormick, CL [1 ]
机构：
[1] Univ So Mississippi, Dept Polymer Sci, Hattiesburg, MS 39406 USA
[2] Univ So Mississippi, Dept Chem & Biochem, Hattiesburg, MS 39406 USA
来源：
MACROMOLECULES | 2002年 / 35卷 / 23期
关键词：
D O I：
10.1021/ma0209996
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
One of the primary advantages of reversible addition-fragmentation chain transfer (RAFT) over other controlled radical polymerization techniques were demonstrated. Controlled structure homopolymers of acrylamido-, methacrylic-, and styrenic-based sulfobetaines were reported employing sodium 4-cyanopentanoic acid dithiobenzoate as the RAFT CTA. Significantly, the polymerizations were conducted directly in aqueous media.
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页码：8663 / 8666
页数：4
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