Three-dimensional layered porous graphene aerogel hydrogen getters

被引:8
|
作者
Zhao, Xingtao
Guo, Yakun
Jing, Zekun
Liu, Xue
Liu, Ruidong
Tao, Ran
Cai, Tianyu
Li, Yingjun
Zhou, Yuanlin
Shuai, Maobing
机构
[1] State Key Laboratory of Environment-friendly Energy Materials, Southwest University of Science and Technology (SWUST), QingLong Street, Sichuan, Mianyang
[2] Science and Technology on Surface Physics and Chemistry Laboratory, No. 9, Huafengxincun, Sichuan, Mianyang
[3] Institute of Materials, China Academy of Engineering Physics (CAEP), Sichuan, Mianyang
基金
中国国家自然科学基金;
关键词
hydrogen diffusion; 3; February; 2022; Hydrogen absorption; Graphene aerogel; Palladium nanocatalyst; CO2; ADSORPTION; OXIDE; PD; TEMPERATURE; STORAGE; NANOCOMPOSITES; PERFORMANCE; REDUCTION; MECHANISM; SURFACES;
D O I
10.1016/j.ijhydene.2022.02.194
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Organic getters are often introduced into sealed systems to remove the excessive reactive hydrogen gas. In this work, the formable graphene aerogel hydrogen getters are prepared by integrating the alkyne-containing molecules (e.g., DEB) into the palladium-loaded threedimensional layered porous graphene aerogel (Pd-GA). The performance of Pd-GA/DEB composite materials in reducing reactive hydrogen gas is examined at pressures of 0.1 -1 bar at a temperature of 25 degrees C, and the hydrogen consumption is measured as a function of time. Results suggest that the hydrogen uptake capability of Pd-GA/DEB getters increases with the loading of Pd particles on the GA and the content of Pd0. The highest hydrogen absorption capacity is up to 215.5 cm3/g, and the hydrogenation rate of DEB molecules is
引用
收藏
页码:15296 / 15307
页数:12
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