Manoyloxide Sesterterpenoids from Salvia mirzayanii

被引：28

作者：

Ebrahimi, Samad N. ^{[1
,2
]}

Farimani, M. Moridi ^{[1
]}

Mirzania, Foroogh ^{[1
]}

Soltanipoor, Mohammad A. ^{[3
]}

De Mieri, Maria ^{[2
]}

Hamburger, Matthias ^{[2
]}

机构：

[1] Shahid Beheshti Univ, Med Plants & Drugs Res Inst, Dept Phytochem, GC, Tehran, Iran

[2] Univ Basel, Dept Pharmaceut Sci, CH-4056 Basel, Switzerland

[3] Hormozgan Agr & Nat Resources Res Ctr, Bandarabbas, Iran

来源：

JOURNAL OF NATURAL PRODUCTS | 2014年 / 77卷 / 04期

基金：

瑞士国家科学基金会;

关键词：

ABSOLUTE-CONFIGURATIONS; ABIETANE DITERPENOIDS; CONSTITUENTS; ANTIBACTERIAL; TERPENOIDS; SAHENDICA;

D O I：

10.1021/np400948n

中图分类号：

Q94 [植物学];

学科分类号：

071001 ;

摘要：

Five new manoyloxide-type sesterterpenes were isolated from aerial parts of Salvia mirzayanii, a species endemic to Iran. The planar structures were established by means of ID and 2D NMR and HRESIMS. Compounds 1-3 differed only in their configurations at C-13 and C-14. Assignment of relative and absolute configurations was achieved by NOESY experiments and by comparison of experimental and simulated ECD spectra of possible stereoisomers. The absolute configurations of 4 and 5 were established in a similar manner.

引用

页码：848 / 854

页数：7

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