Oxidative Allylic Amination Reactions of Unactivated Olefins - At the Frontiers of Palladium and Selenium Catalysis

被引：31
作者：
Breder, Alexander [1 ]
机构：
[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany
来源：
SYNLETT | 2014年 / 25卷 / 07期
关键词：
alkenes; C-N bond construction; catalysis; oxidation; chalcogens; transition metals; C-H AMINATION; N BOND FORMATION; PALLADIUM(II)-CATALYZED CYCLIZATION; ASYMMETRIC HYDROAMINATION; STEP ECONOMY; ALKENES; AMIDATION; FUNCTIONALIZATION; NUCLEOPALLADATION; ISOINDOLINONES;
D O I：
10.1055/s-0033-1340625
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The direct oxidative conversion of simple, nonactivated alkenes into allylic amine derivatives represents a profound challenge to contemporary chemical synthesis. This article provides an overview on recent methodological developments and applications in the realm of modern palladium- and selenium-catalyzed oxidative allylic amination reactions.
引用
收藏
页码：899 / 904
页数：6
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