Snow and firn properties and air-snow transport processes at Summit, Greenland

Snow-air exchange processes affect the chemistry of the atmosphere as well as the chemistry of underlying snow and firn. An understanding of the transport processes is important for quantifying and predicting changes in atmospheric chemistry and also for improving ice core interpretation. This paper focuses on the nature of diffusive and advective (ventilation) interstitial transport processes at Summit, Greenland. Field measurements of snow and firn density, permeability and microstructure are presented and compared with measurements from previous years. Density and permeability profiles follow similar general patterns from year to year; however, the specifics of the profiles show interannual variation. Field measurements of the diffusion of an inert tracer gas, SF6, through the surface wind pack yields an SF6 diffusion coefficient for the June 2000 surface wind pack at Summit of similar to0.06 cm(2)/s; the tortuosity of the surface wind pack was 0.5. The first direct measurements of interstitial air flow in snow due to natural ventilation in undisturbed snow are presented, for light (3 m/s) winds and moderately strong (9 m/s) winds in a hoar layer 15 cm beneath the surface. The measurements during light winds showed results characteristic of diffusion profiles, while the measurements under strong winds showed evidence of ventilation. The interstitial air flow velocities are consistent with previous modeling results. Published by Elsevier Science Ltd.