Tailored Ferroelectric Responses and Enhanced Energy Density in PVDF-Based Homopolymer/Terpolymer Blends

被引:15
作者
Gao, Lei [1 ]
He, Jinliang [1 ]
Hu, Jun [1 ]
Li, Yang [1 ]
机构
[1] Tsinghua Univ, Dept Elect Engn, Key Lab Power Syst, Beijing 100084, Peoples R China
关键词
blends; dielectric properties; films;
D O I
10.1002/app.40994
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Blend of polymers is an effective way to tailor the ferroelectric responses and improve the energy storage properties of polymers. In this work, the microstructure and dielectric responses of the blends of poly(vinylidene fluoride) (PVDF) and poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene) [P(VDF-TrFE-CFE)] have been studied. It is found that the addition of PVDF disturbs the crystallization process of P(VDF-TrFE-CFE), leading to lower crystallinity and smaller crystalline size. The aforementioned microstructure changes result in tailored ferroelectric responses. Dielectric responses show that the blend with 10 wt % PVDF achieves larger polarization response under high electric field (above 300 MV/m) due to the interfacial polarization. Because of the tailoring effect and the interfacial polarization, the blend with 10 wt % PVDF exhibits higher energy density and efficiency. Moreover, the breakdown strength (E-b) is also improved by adding a small amount of PVDF into the terpolymer. (C) 2014 Wiley Periodicals, Inc.
引用
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页数:7
相关论文
共 28 条
[1]   Poly(ethylene glycol)/acrylic polymer blends for latent heat thermal energy storage [J].
Alkan, Cemil ;
Sari, Ahmet ;
Uzun, Orhan .
AICHE JOURNAL, 2006, 52 (09) :3310-3314
[2]  
Bai Y., 2001, P 12 IEEE INT S APPL, VI and II, P801
[3]   Phase transitions and ferroelectric relaxor behavior in P(VDF-TrFE-CFE) terpolymers [J].
Bao, Hui-Min ;
Song, Jiao-Fan ;
Zhang, Juan ;
Shen, Qun-Dong ;
Yang, Chang-Zheng ;
Zhang, Q. M. .
MACROMOLECULES, 2007, 40 (07) :2371-2379
[4]  
Baojin C., 2008, APPL PHYS LETT, V93
[5]   Recent advances in highly electrostrictive P(VDF-TrFE-CFE) terpolymers [J].
Bauer, F. ;
Fousson, E. ;
Zhang, Q. M. .
IEEE TRANSACTIONS ON DIELECTRICS AND ELECTRICAL INSULATION, 2006, 13 (05) :1149-1154
[6]  
Chen Q., 2007, APPL PHYS LETT, V91
[7]   A polymer blend approach to tailor the ferroelectric responses in P(VDF-TrFE) based copolymers [J].
Chen, Xiang-Zhong ;
Li, Xinyu ;
Qian, Xiao-Shi ;
Wu, Shan ;
Lu, Sheng-Guo ;
Gu, Hai-Ming ;
Lin, Minren ;
Shen, Qun-Dong ;
Zhang, Q. M. .
POLYMER, 2013, 54 (09) :2373-2381
[8]  
Chu BJ, 2006, IEEE T DIELECT EL IN, V13, P1162, DOI 10.1109/TDEI.2006.1714943
[9]   A dielectric polymer with high electric energy density and fast discharge speed [J].
Chu, Baojin ;
Zhou, Xin ;
Ren, Kailiang ;
Neese, Bret ;
Lin, Minren ;
Wang, Qing ;
Bauer, F. ;
Zhang, Q. M. .
SCIENCE, 2006, 313 (5785) :334-336
[10]  
Dissado L.A., 1992, Electrical Degradation and Breakdown in Polymers, P199