From rational octahedron design to reticulation serendipity.: A thermally stable rare earth polymeric disulfonate family with CdI2-like structure, bifunctional catalysis and optical properties

被引：80

作者：

Snejko, N ^{[1
]}

Cascales, C ^{[1
]}

Gomez-Lor, B ^{[1
]}

Gutiérrez-Puebla, E ^{[1
]}

Iglesias, M ^{[1
]}

Ruiz-Valero, C ^{[1
]}

Monge, MA ^{[1
]}

机构：

[1] CSIC, Inst Ciencia Mat, E-28049 Madrid, Spain

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 13期

关键词：

D O I：

10.1039/b202639b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new family of lanthanide disulfonates Ln(OH)(NDS) (H2O), (Ln = La, Pr and Nd; NDS = 1,5- naphthalenedisulfonate) was designed and hydrothermally synthesized; this is the first example of a disulfonate ligand coordinated to six different Ln atoms; these materials, with high thermal stability, act as active and selective bifunctional catalysts in oxidation and epoxide ring opening; strong luminescence from the optically active Nd center was observed.

引用

页码：1366 / 1367

页数：2

共 16 条

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