Vibration-rotation tunneling spectra of the water pentamer: Structure and dynamics

被引：289
作者：
Liu, K
Brown, MG
Cruzan, JD
Saykally, RJ
机构：
[1] Department of Chemistry, University of California, Berkeley
来源：
SCIENCE | 1996年 / 271卷 / 5245期
关键词：
D O I：
10.1126/science.271.5245.62
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
Far-infrared laser vibration-rotation tunneling spectroscopy was used to measure an intermolecular vibration (81.19198 wave numbers) of the isolated water (D2O) pentamer, Relational analysis supports the chiral, slightly puckered ring structure predicted by theory, The experimentally deduced interoxygen separations for the water clusters up to the pentamer showed exponential convergence toward the corresponding distance in bulk phase water.
引用
收藏
页码：62 / 64
页数：3
相关论文
共 34 条
[1]  
BLAKE GA, 1991, REV SCI INSTRUM, V62, P1701, DOI 10.1063/1.1142410
[2]   SIMULATION OF THE INTERMOLECULAR VIBRATIONAL-SPECTRA OF LIQUID WATER AND WATER CLUSTERS [J].
BOSMA, WB ;
FRIED, LE ;
MUKAMEL, S .
JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (06) :4413-4421
[3]   THEORETICAL-STUDY OF WATER CLUSTERS .1. PENTAMER [J].
BURKE, LA ;
JENSEN, JO ;
JENSEN, JL ;
KRISHNAN, PN .
CHEMICAL PHYSICS LETTERS, 1993, 206 (1-4) :293-296
[4]   SOLVATED WATER-MOLECULES AND HYDROGEN-BRIDGED NETWORKS IN LIQUID WATER [J].
CORONGIU, G ;
CLEMENTI, E .
JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (03) :2241-2249
[5]   Quantifying hydrogen bond cooperativity in water: VRT spectroscopy of the water tetramer [J].
Cruzan, JD ;
Braly, LB ;
Liu, K ;
Brown, MG ;
Loeser, JG ;
Saykally, RJ .
SCIENCE, 1996, 271 (5245) :59-62
[6]   STRUCTURE OF WATER DIMER FROM MOLECULAR-BEAM ELECTRIC RESONANCE SPECTROSCOPY [J].
DYKE, TR ;
MACK, KM ;
MUENTER, JS .
JOURNAL OF CHEMICAL PHYSICS, 1977, 66 (02) :498-510
[7]   (H2O)2 - SPECTROSCOPY, STRUCTURE AND DYNAMICS [J].
FRASER, GT .
INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY, 1991, 10 (02) :189-206
[8]   IR SPECTROSCOPY OF SIZE-SELECTED CLUSTERS AT 3-MU-M WAVELENGTH [J].
HUISKEN, F ;
KALOUDIS, M ;
KULCKE, A ;
VOELKEL, D .
INFRARED PHYSICS & TECHNOLOGY, 1995, 36 (01) :171-178
[9]   THE THERMODYNAMICS AND MOLECULAR STRUCTURE OF CYCLOPENTANE [J].
KILPATRICK, JE ;
PITZER, KS ;
SPITZER, R .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1947, 69 (10) :2483-2488
[10]   REVISITING SMALL CLUSTERS OF WATER-MOLECULES [J].
KIM, KS ;
DUPUIS, M ;
LIE, GC ;
CLEMENTI, E .
CHEMICAL PHYSICS LETTERS, 1986, 131 (06) :451-456
1234