Synthesis of digermylene-stabilized linear tetraboronate and boroxine

被引：33

作者：

Wu, Yile ^{[1
,2
]}

Liu, Liu ^{[1
,2
]}

Su, Jue ^{[1
,2
]}

Yan, Kaili ^{[1
,2
]}

Zhu, Jun ^{[3
]}

Zhao, Yufen ^{[1
,2
,4
]}

机构：

[1] Xiamen Univ, Coll Chem & Chem Engn, Dept Chem, Xiamen 361005, Fujian, Peoples R China

[2] Xiamen Univ, Coll Chem & Chem Engn, Key Lab Chem Biol Fujian Prov, Xiamen 361005, Fujian, Peoples R China

[3] Xiamen Univ, Coll Chem & Chem Engn, Key Lab Theoret & Computat Chem, State Key Lab Phys Chem Solid Surfaces & Fujian P, Xiamen 361005, Fujian, Peoples R China

[4] Tsinghua Univ, Dept Chem, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Minist Educ, Beijing 100084, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 08期

关键词：

STRUCTURAL-CHARACTERIZATION; NUCLEOPHILIC-ADDITION; H BOND; COVALENT; GERMYLENE; REACTIVITY; AMMONIA; FUNCTIONALIZATION; HETEROBOROXINES; ACTIVATION;

D O I：

10.1039/c5cc09330a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two newly discovered linear compounds tetraboronate and boroxine stabilized by digermylene are reported, which feature a B4O5 chain and a B3O3 ring, respectively. DFT calculations reveal that not only can digermylene stabilize the electron-deficient boron centers, but also increase the energies of the LUMOs of the boron moiety. Our results provide a hint for the development of boronate covalent organic frameworks.

引用

页码：1582 / 1585

页数：4

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