Biaryl synthesis from two different aryl halides with tri(2-furyl)germane

被引：65

作者：

Nakamura, T ^{[1
]}

Kinoshita, H ^{[1
]}

Shinokubo, H ^{[1
]}

Oshima, K ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Kyoto 6068501, Japan

来源：

ORGANIC LETTERS | 2002年 / 4卷 / 18期

关键词：

D O I：

10.1021/ol026613t

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] The coupling reaction of germanium compounds with aryl halides has been developed. The Pd(0)-catalyzed reaction of aryl halides with tri(2-furyl)germane provides aryltri(2-furyl)germanes in good yield. The cross-coupling reaction of aryltri(2-furyl)germanes with aryl halides is acheived. This allows facile synthesis of unsymmetrical biaryls from two different aryl halides.

引用

页码：3165 / 3167

页数：3

共 25 条

[1]

[Anonymous], 1999, J CHEM EDUC

[2] PALLADIUM-CATALYZED FORMYLATION OF ORGANIC HALIDES WITH CARBON-MONOXIDE AND TIN HYDRIDE [J].

BAILLARGEON, VP ;

STILLE, JK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (03) :452-461

[3] PdCl2-catalyzed reduction of organic halides by triethylsilane [J].

Boukherroub, R ;

Chatgilialoglu, C ;

Manuel, G .

ORGANOMETALLICS, 1996, 15 (05) :1508-1510

[4] Highly stereospecific, palladium-catalyzed cross-coupling of alkenylsilanols [J].

Denmark, SE ;

Wehrli, D .

ORGANIC LETTERS, 2000, 2 (04) :565-568

[5] Synthesis of unsymmetrical biaryls from arylsilacyclobutanes [J].

Denmark, SE ;

Wu, ZC .

ORGANIC LETTERS, 1999, 1 (09) :1495-1498

[6] Highly stereospecific, cross-coupling reactions of alkenylsilacyclobutanes [J].

Denmark, SE ;

Choi, JY .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (24) :5821-5822

[7]

Denmark SE, 2000, SYNTHESIS-STUTTGART, P999

[8]

Diederich F., 1998, METAL CATALYZED CROS, DOI DOI 10.1002/9783527612222

[9] Palladium-catalyzed cross-coupling of silanols, silanediols, and silanetriols promoted by silver(I) oxide [J].

Hirabayashi, E ;

Mori, A ;

Kawashima, J ;

Suguro, M ;

Nishihara, Y ;

Hiyama, T .

JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (17) :5342-5349

[10] A new transformation of silanols. Palladium-catalyzed cross-coupling with organic halides in the presence of silver(I) oxide [J].

Hirabayashi, K ;

Kawashima, J ;

Nishihara, Y ;

Mori, A ;

Hiyama, T .

ORGANIC LETTERS, 1999, 1 (02) :299-301

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