Application of the scaled particle theory to the glass transition of hard spheres

被引:7
|
作者
Baeyens, B
Verschelde, H
机构
[1] Department of Mathematical Physics and Astronomy, University of Gent, B-9000 Gent
来源
关键词
D O I
10.1007/s002570050287
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
In a previous article [1], an improved approach to the scaled particle theory of Reiss et al. was presented. As a result, we obtained a Pade-like expression of the compressibility factor of the fluid state. That expression contains two parameters p(1) and p(2), which we were able to calculate. In this paper we find other sets of values for p(1) and p(2). Two of these sets yield equations of state which agree with the simulation results of the glassy states obtained by Woodcock and Speedy. The calculations are based on two assumptions: firstly, that second order phase transitions may occur and secondly, that a hard sphere glass contains a fluid-like and a solid-like part. As an additional result, we found an upper and a lower limit for the fluid densities at which glass transitions may occur.
引用
收藏
页码:255 / 259
页数:5
相关论文
共 50 条
  • [21] RADIAL-DISTRIBUTION FUNCTION FOR HARD SPHERES FROM SCALED PARTICLE THEORY, AND AN IMPROVED EQUATION OF STATE
    REISS, H
    CASBERG, RV
    JOURNAL OF CHEMICAL PHYSICS, 1974, 61 (03): : 1107 - 1114
  • [22] SCALED PARTICLE THEORY FOR NON-ADDITIVE HARD SPHERES GENERAL THEORY AND SOLUTION OF WIDOM-ROWLINSON MODEL
    BERGMANN, E
    MOLECULAR PHYSICS, 1976, 32 (01) : 237 - 256
  • [23] Augmented scaled particle theory for a hard disk fluid
    Qiao, C. Z.
    Zhao, S. L.
    Dong, W.
    JOURNAL OF MOLECULAR LIQUIDS, 2022, 368
  • [24] SCALED PARTICLE THEORY FOR MIXTURES OF HARD CONVEX PARTICLES
    GIBBONS, RM
    MOLECULAR PHYSICS, 1970, 18 (06) : 809 - &
  • [25] THE GLASS-TRANSITION IN COLLOIDAL HARD-SPHERES
    VANMEGEN, W
    UNDERWOOD, SM
    JOURNAL OF PHYSICS-CONDENSED MATTER, 1994, 6 : A181 - A186
  • [26] Glass transition of dense fluids of hard and compressible spheres
    Berthier, Ludovic
    Witten, Thomas A.
    PHYSICAL REVIEW E, 2009, 80 (02)
  • [27] Freezing, melting and the glass transition in a suspension of hard spheres
    van Megen, W
    JOURNAL OF PHYSICS-CONDENSED MATTER, 2002, 14 (33) : 7699 - 7717
  • [28] Glass transition line for the system of charged hard spheres
    Cardenas, M
    Tosi, MP
    SOLID STATE COMMUNICATIONS, 2005, 133 (10) : 667 - 670
  • [29] Glass transition of quantum hard spheres in high dimensions
    Winer, Michael
    Baldwin, Christopher L.
    Barney, Richard
    Galitski, Victor
    Swingle, Brian
    PHYSICAL REVIEW E, 2024, 109 (04)
  • [30] Thermodynamic signature of the dynamic glass transition in hard spheres
    Hermes, Michiel
    Dijkstra, Marjolein
    JOURNAL OF PHYSICS-CONDENSED MATTER, 2010, 22 (10)