Valence band ordering in β-Ga2O3 studied by polarized transmittance and reflectance spectroscopy

被引:303
作者
Onuma, Takeyoshi [1 ,2 ]
Saito, Shingo [2 ]
Sasaki, Kohei [2 ,3 ]
Masui, Tatekazu [3 ]
Yamaguchi, Tomohiro [1 ]
Honda, Tohru [1 ]
Higashiwaki, Masataka [2 ]
机构
[1] Kogakuin Univ, Dept Appl Phys, Hachioji, Tokyo 1920015, Japan
[2] Natl Inst Informat & Commun Technol, Koganei, Tokyo 1848795, Japan
[3] Tamura Corp, Sayama, Saitama 3501328, Japan
关键词
ABSORPTION; GROWTH;
D O I
10.7567/JJAP.54.112601
中图分类号
O59 [应用物理学];
学科分类号
摘要
The polarized transmittance and reflectance spectra of beta-Ga2O3 crystals are investigated, and the data are interpreted in terms of the monoclinic crystal band structure. The energies of the absorption edge can be divided into six ranges, and these ranges can be assigned to the transitions from the valence bands to the conduction band minimum according to the selection rules. The indirect bandgap-energy of 4.43 eV is smaller than the direct bandgap-energy of 4.48 eV at RT; and the energy difference of 0.05 eV nearly matches the theoretically calculated values of 0.03-0.04 eV. (C) 2015 The Japan Society of Applied Physics
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页数:5
相关论文
共 27 条
[1]  
[Anonymous], 1971, Chemical Applications of Group Theory
[2]   RELATION BETWEEN ELECTRON BAND-STRUCTURE AND MAGNETIC BISTABILITY OF CONDUCTION ELECTRONS IN BETA-GA2O3 [J].
BINET, L ;
GOURIER, D ;
MINOT, C .
JOURNAL OF SOLID STATE CHEMISTRY, 1994, 113 (02) :420-433
[3]   CRYSTAL STRUCTURE OF BETA-GA2O3 [J].
GELLER, S .
JOURNAL OF CHEMICAL PHYSICS, 1960, 33 (03) :676-684
[4]   First-principles study of the structural, electronic, and optical properties of Ga2O3 in its monoclinic and hexagonal phases [J].
He, Haiying ;
Orlando, Roberto ;
Blanco, Miguel A. ;
Pandey, Ravindra ;
Amzallag, Emilie ;
Baraille, Isabelle ;
Rerat, Michel .
PHYSICAL REVIEW B, 2006, 74 (19)
[5]   Electronic and thermodynamic properties of β-Ga2O3 [J].
He, Haiying ;
Blanco, Miguel A. ;
Pandey, Ravindra .
APPLIED PHYSICS LETTERS, 2006, 88 (26)
[6]   Depletion-mode Ga2O3 metal-oxide-semiconductor field-effect transistors on β-Ga2O3 (010) substrates and temperature dependence of their device characteristics [J].
Higashiwaki, Masataka ;
Sasaki, Kohei ;
Kamimura, Takafumi ;
Wong, Man Hoi ;
Krishnamurthy, Daivasigamani ;
Kuramata, Akito ;
Masui, Takekazu ;
Yamakoshi, Shigenobu .
APPLIED PHYSICS LETTERS, 2013, 103 (12)
[7]   Gallium oxide (Ga2O3) metal-semiconductor field-effect transistors on single-crystal β-Ga2O3 (010) substrates [J].
Higashiwaki, Masataka ;
Sasaki, Kohei ;
Kuramata, Akito ;
Masui, Takekazu ;
Yamakoshi, Shigenobu .
APPLIED PHYSICS LETTERS, 2012, 100 (01)
[8]  
Klingshirn C.F., 2012, Semiconductor Optics
[9]   Sol-gel prepared β-Ga2O3 thin films for ultraviolet photodetectors [J].
Kokubun, Yoshihiro ;
Miura, Kasumi ;
Endo, Fumie ;
Nakagomi, Shinji .
APPLIED PHYSICS LETTERS, 2007, 90 (03)
[10]   ABSORPTION AND REFLECTION OF VAPOR GROWN SINGLE-CRYSTAL PLATELETS OF BETA-GA2O3 [J].
MATSUMOTO, T ;
AOKI, M ;
KINOSHITA, A ;
AONO, T .
JAPANESE JOURNAL OF APPLIED PHYSICS, 1974, 13 (10) :1578-1582