Synthesis, crystal structure, vibrational spectroscopy and expected magnetic properties of a new bismuth nickel phosphate Ni(BiO)2(PO4)(OH) with a namibite-type structure

被引：8

作者：

Aksenov, Sergey M. ^{[1
,2
]}

Mironov, Vladimir S. ^{[2
]}

Borovikova, Elena Yu. ^{[3
]}

Yamnova, Natalia A. ^{[3
]}

Gurbanova, Olga A. ^{[3
]}

Volkov, Anatoly S. ^{[3
]}

Dimitrova, Olga V. ^{[3
]}

Deyneko, Dina V. ^{[4
]}

机构：

[1] RAS, Inst Organoelement Cpds, Vavilova St 28, Moscow 119334, Russia

[2] Russian Acad Sci, Inst Crystallog, Fed Sci Res Ctr Crystallog & Photon, Leninskiy Prospekt 59, Moscow 119333, Russia

[3] Moscow MV Lomonosov State Univ, Fac Geol, Moscow 119991, Russia

[4] Moscow MV Lomonosov State Univ, Fac Chem, Moscow 119991, Russia

来源：

SOLID STATE SCIENCES | 2017年 / 63卷

关键词：

Hydrothermal synthesis; Bismuth nickel oxophosphate; Namibite; Single-crystal X-ray diffraction; Magnetic properties; BOND-VALENCE PARAMETERS; 1D SINGLE-CHAIN; BI3+/M2+ OXYPHOSPHATE; CONTINUOUS SERIES; RIBBON-LIKE; 2D PLANES; CO; INTERGROWTHS; PAGANOITE; MINERALS;

D O I：

10.1016/j.solidstatesciences.2016.11.003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Single crystals of a novel Bi-Ni phosphate Ni(BiO)(2)(PO4)(OH) were synthesized by a hydrothermal method in Bi2O3 NiO K2O P2O5 system and characterized by X-ray structure analysis and IR and Raman spectroscopy. This compound crystallizes in a namibite type structure with triclinic unit-cell parameters, a = 63220 (3) angstrom, b = 6.9043 (4) angstrom, c = 7.5641 (5) angstrom, alpha= 90.483 (5)degrees, beta = 107.219 (5)degrees, gamma = 110.758 (5)degrees; V= 292.51 (3) angstrom(3); space group P (1) over bar (No. 2). Crystal structure is refined to final R-1 = 4.09 using 1637 I > 2 sigma.(I). The structure contains infinite chains (Ni(OH)(PO4)}infinity built of corner-sharing NiO6 octahedra. Microscopic calculations of the intra- and interchain J (Ni-Ni) exchange parameters suggests possible S = 1 antiferromagnet chain behavior of this compound at low temperatures. (C) 2016 Elsevier Masson SAS. All rights reserved.

引用

页码：16 / 22

页数：7

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