Design, syntheses and extraction properties of novel bis-calix[arene] and tris-calix[4]arene containing two kinds of calix[4]arene derivative units

被引：13

作者：

Yang, Fafu ^{[1
]}

Ji, Yanqing ^{[1
]}

Zheng, Linlu ^{[1
]}

Guo, Hongyu ^{[1
]}

Lin, Jianrong ^{[1
]}

机构：

[1] Fujian Normal Univ, Dept Chem, Fuzhou 350007, Peoples R China

来源：

SUPRAMOLECULAR CHEMISTRY | 2006年 / 18卷 / 03期

关键词：

bis-calix[4]arene; tris-calix[4]arene; synthesis; complexation; cations; amino acid;

D O I：

10.1080/10610270500398706

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By condensation of calix[4]arene 1,3-bis-hydrazide derivative 5 and calix[4]arene mono-benzaldehyde derivative 2, and then intramolecular bridging with triethylene glycol ditosylates, two novel tris-calix[4]arenes 6 and 7 containing two kinds of calix[4]arene derivative units were prepared in reasonable yield. When reacting compound 5 with calix[4]arene 1,3-bis-benzaldehyde derivative 3, novel bis-calix[4]arene 8 containing two different calix[4]arene derivative units was obtained in high yield. The extraction experiments showed that the new hosts 6, 7 and 8 possessed excellent complexation abilities towards metal cations and alpha-amino acids. Tris-calix[4]arene 7 showed good complexation selectivity towards Ag+ and basic alpha-arnino acid.

引用

页码：177 / 181

页数：5

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