Facile synthesis and photocatalytic disinfection of boron self-doped TiO2 nanosheets

被引:13
作者
Wang, Bin [1 ]
Lu, Xiao-Ying [1 ]
Xuan, Jin [1 ,2 ]
Leung, Michael K. H. [1 ]
机构
[1] City Univ Hong Kong, Sch Energy & Environm, Abil R&D Energy Res Ctr, Hong Kong, Hong Kong, Peoples R China
[2] E China Univ Sci & Technol, Sch Mech & Power Engn, State Key Lab Chem Engn, Shanghai 200237, Peoples R China
关键词
TiO2; nanosheets; Nanocrystalline materials; Electron microscopy; XPS; Photocatalysis; VISIBLE-LIGHT; NANOTUBE ARRAY; DYE; DEGRADATION; PERCENTAGE;
D O I
10.1016/j.matlet.2013.09.125
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this study, a facile hydrothermal method was successfully developed to synthesize boron self-doped TiO2 nanosheets directly from TiB2 powders. XRD and TEM results suggested that the as-prepared TiO2 were pure anatase phase and showed a sheet morphology with reactive (001) facets. XPS analysis revealed the presence of boron as dopants by substituting oxygen atom in TiO2 nanosheets. The effect of HBF4 on TiO2 synthesis was also investigated. Photocatalytic disinfection experimental study implied that boron self-doped TiO2 exhibited better performance than P25 under visible light irradiation. The enhanced photocatalytic effect was ascribed to the nanosheet morphology with reactive (001) facets and self-doping of boron in TiO2. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:57 / 59
页数:3
相关论文
共 16 条
[1]   Photocatalytic decolorization of anthraquinonic dye by TiO2 thin film under UVA and visible-light irradiation [J].
Ao, C. H. ;
Leung, M. K. H. ;
Lam, Ringo C. W. ;
Leung, Dennis Y. C. ;
Vrijmoed, Lilian L. P. ;
Yam, W. C. ;
Ng, S. P. .
CHEMICAL ENGINEERING JOURNAL, 2007, 129 (1-3) :153-159
[2]   Effects of boron doping on photocatalytic activity and microstructure of titanium dioxide nanoparticles [J].
Chen, Daimei ;
Yang, Dong ;
Wang, Qun ;
Jiang, Zhongyi .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (12) :4110-4116
[3]   Graphene enhanced photocatalytic hydrogen evolution performance of dye-sensitized TiO2 under visible light irradiation [J].
Chen, Yajing ;
Mou, Zhigang ;
Yin, Shunli ;
Huang, Hui ;
Yang, Ping ;
Wang, Xiaomei ;
Du, Yukou .
MATERIALS LETTERS, 2013, 107 :31-34
[4]   Synthesis of Titania Nanosheets with a High Percentage of Exposed (001) Facets and Related Photocatalytic Properties [J].
Han, Xiguang ;
Kuang, Qin ;
Jin, Mingshang ;
Xie, Zhaoxiong ;
Zheng, Lansun .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (09) :3152-+
[5]   Photocatalytic degradation of pathogenic bacteria with AgI/TiO2 under visible light irradiation [J].
Hu, Chun ;
Guo, Jian ;
Qu, Jiuhui ;
Hu, Xuexiang .
LANGMUIR, 2007, 23 (09) :4982-4987
[6]   Effective visible light-activated B-Doped and B,N-Codoped TiO2 photocatalysts [J].
In, Suil ;
Orlov, Alexander ;
Berg, Regina ;
Garcia, Felipe ;
Pedrosa-Jimenez, Sergio ;
Tikhov, Mintcho S. ;
Wright, Dominic S. ;
Lambert, Richard M. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (45) :13790-+
[7]   Facile method for fabricating boron-doped TiO2 nanotube array with enhanced photoelectrocatalytic properties [J].
Li, Jingyuan ;
Lu, Na ;
Quan, Xie ;
Chen, Shuo ;
Zhao, Huimin .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2008, 47 (11) :3804-3808
[8]   Visible Light Responsive Nitrogen Doped Anatase TiO2 Sheets with Dominant {001} Facets Derived from TiN [J].
Liu, Gang ;
Yang, Hua Gui ;
Wang, Xuewen ;
Cheng, Lina ;
Pan, Jian ;
Lu, Gao Qing ;
Cheng, Hui-Ming .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (36) :12868-+
[9]   Fabrication of boron-doped TiO2 nanotube array electrode and investigation of its photoelectrochemical capability [J].
Lu, Na ;
Quan, Xie ;
Li, JingYuan ;
Chen, Shuo ;
Yu, HongTao ;
Chen, GuoHua .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (32) :11836-11842
[10]   A review and recent developments in photocatalytic water-splitting using TiO2 for hydrogen production [J].
Ni, Meng ;
Leung, Michael K. H. ;
Leung, Dennis Y. C. ;
Sumathy, K. .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2007, 11 (03) :401-425