Conjugates of Bispidine and Monoterpenoids as Ligands of Metal Complex Catalysts for the Henry Reaction

被引：18

作者：

Mozhaitsev, E. S. ^{[1
]}

Ponomarev, K. Y. ^{[1
]}

Patrusheva, O. S. ^{[1
]}

Medvedko, A. V. ^{[2
]}

Dalinger, A. I. ^{[2
]}

Rogachev, A. D. ^{[1
]}

Komarova, N. I. ^{[1
]}

Korchagina, D. V. ^{[1
]}

Suslov, E. V. ^{[1
]}

Volcho, K. P. ^{[1
]}

Salakhutdinov, N. F. ^{[1
]}

Vatsadze, S. Z. ^{[2
]}

机构：

[1] Russian Acad Sci, Novosibirsk Organ Chem Inst, Siberian Branch, Novosibirsk 630090, Russia

[2] Lomonosov Moscow State Univ, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2020年 / 56卷 / 11期

基金：

俄罗斯科学基金会;

关键词：

asymmetric catalysis; cage amines; bispidines; monoterpenoids; Henry reaction; copper complexes; zinc complexes; CHIRAL SCHIFF-BASES; ASYMMETRIC OXIDATION; ACIDS;

D O I：

10.1134/S1070428020110123

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A number of chiral chelating conjugates combining a bispidine central backbone and one or two pinene side fragments were synthesized. It was shown for the first time that the synthesized compounds are capable to act as catalysts in the Henry reaction both individually and in the presence of metal salts. It was found that the best catalytic results were shown for bis-tertiary amine combining bispidinone and two (-)-myrtenol fragments, and copper as well as zinc acetates.

引用

页码：1969 / 1981

页数：13

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