Preparation and Characterization of Micron-Sized PMMA/SiO2 Composite Microspheres

被引:15
作者
Mu, Ju [1 ]
Zhou, Yuming [1 ]
Bu, Xiaohai [1 ]
Zhang, Tao [1 ]
机构
[1] Southeast Univ, Jiangsu Optoelect Funct Mat & Engn Lab, Sch Chem & Chem Engn, Nanjing 211189, Jiangsu, Peoples R China
关键词
Composite microspheres; PMMA; SiO2; Micron-sized; POLY(METHYL METHACRYLATE); PMMA; BEHAVIOR; SILICA;
D O I
10.1007/s10904-014-0047-7
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Micron PMMA microspheres which had PVP-g-PMMA graft polymers on the surface were prepared via a dispersion polymerization method by using the PVP K-30 as the dispersant. Because of the PVP-g-PMMA graft polymers, SiO2 nanoparticles were successfully introduced to the PMMA microsphere's surface through the TEOS hydrolysis method. SEM and other tests suggested micron-sized PMMA/SiO2 composite microspheres were successfully synthesized. SiO2 nanoparticles could grow on the PMMA microspheres, probably because SiO2 was attracted chemically to the carbonyl bonds on the PVP molecules.
引用
收藏
页码:776 / 779
页数:4
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