Enantioselective allylic substitution catalyzed by an iridium complex: remarkable effects of the counter cation

被引：81

作者：

Fuji, K ^{[1
]}

Kinoshita, N

Tanaka, K

Kawabata, T

机构：

[1] Kyoto Univ, Chem Res Inst, Kyoto 6110011, Japan

[2] Univ Shizuoka, Sch Pharmaceut Sci, Shizuoka 4228526, Japan

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 22期

关键词：

D O I：

10.1039/a907680h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Allylic substitution of a methyl carbonate of cinnamyl alcohol with the anion of dimethyl malonate gave the branched olefin with high enantioselectivity in the presence of (S)-1,1'-binaphthyl-2,2'-diyl phenyl phosphite when a combination of lithium and zinc was used as counter cation.

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收藏

页码：2289 / 2290

页数：2

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