Synthesis of ruthenium N-heterocyclic carbene complexes and their catalytic activity for β-alkylation of tertiary cyclic amines

被引：15

作者：

Ozdemir, Ismail ^{[1
]}

Dusunceli, Serpil Demir ^{[1
]}

Kaloglu, Nazan ^{[1
]}

Achard, Mathieu ^{[2
]}

Bruneau, Christian ^{[2
]}

机构：

[1] Inonu Univ, Catalysis Res & Applicat Ctr, TR-44280 Malatya, Turkey

[2] Univ Rennes 1, UMR6226, Inst Sci Chim Rennes, Ctr Catalyse & Chim Verte, F-35042 Rennes, France

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2015年 / 799-800卷

关键词：

N-Heterocyclic carbene; Ruthenium; Cyclic amine; Catalysis; OLEFIN METATHESIS; ALKENE METATHESIS; LIGAND PRECURSORS; FACILE SYNTHESIS; PALLADIUM; RACEMIZATION; EXCHANGE; IMIDAZOL(IN)IUM-2-CARBOXYLATES; HYDROGENATION; ACTIVATION;

D O I：

10.1016/j.jorganchem.2015.10.011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The novel ruthenium N-Heterocyclic carbene complexes are synthesized, and characterized by studying its H-1, C-13, elemental analysis, and X-ray. These complexes have been reported as promising catalyst for beta C-H bond functionalization of tertiary cyclic amines through hydrogen autotransfers in the presence of external acidic additive. The new catalytic products were characterized by H-1 NMR, C-13 NMR spectroscopic methods. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：311 / 315

页数：5

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