NHC ligand-powered palladium-catalyzed carbonylative C-S bond cleavage of vinyl sulfides: efficient access to tert-butyl arylacrylates

被引：2
作者：
Xu, Jian-Xing [1 ]
Zhao, Fengqian [2 ]
Wu, Xiao-Feng [1 ,2 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China
[2] Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2020年 / 18卷 / 48期
关键词：
CARBON-MONOXIDE; CONJUGATE ADDITION; COMPLEXES; ESTERS; TRANSFORMATION; ACTIVATION; KETONES; AMINES;
D O I：
10.1039/d0ob02043e
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A method for palladium-catalyzed carbonylative C-S bond activation of divinyl sulfides to synthesize numerous tert-(E)-butyl arylacry-lates under 1 bar of CO has been developed. Employing electron-rich NHC as the ligand, the electron-rich and stabilized palladium complex trend to oxidative addition to the relatively inert C-S bond and decreased the poisoning effect of sulfide and CO; a series of tert-(E)-butyl acrylates were obtained in moderate to good yields.
引用
收藏
页码：9796 / 9799
页数：4
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