Synthesis, crystal structure and properties of the coordination polymer [HgI2(btx)]n (btx=1-[4-(1H-1,2,4-triazol-1-ylmethyl)benzyl]-1H-1,2,4-triazole)

被引：0

作者：

Xu, H ^{[1
]}

Meng, XR ^{[1
]}

Han, HY ^{[1
]}

Wang, X ^{[1
]}

Hou, HW ^{[1
]}

机构：

[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2004年 / 20卷 / 09期

关键词：

coordination polymer; crystal structure; thermal analysis; luminescence spectroscopic property;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel one-dimension coordination polymer [HgI2(btx)](n) was synthesized through the reaction of alpha, alpha'-dichloro-p-xylene and HgI2 in mixed MeOH-THF (1:1) solution. The compound was characterized by X-ray crystallography and crystallizes in orthorhombic with space group Pnma. The cell parameters of the title compound are: a=0.9363(2) nm, b=1.7694(4) nm, c=1.0322(2) nm, alpha=90degrees. Attractive I...I interactions link HgI2(btx) chains directly resulting in the formation of three-dimensional network structure. In addition, the compound shows better luminescence spectroscopic property in the solid state, and is thermally stable below 126 degreesC.

引用

页码：1089 / 1092

页数：4

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