Using carbon dioxide and its sulfur analogues as monomers in polymer synthesis

被引：91

作者：

Luo, Ming ^{[1
]}

Li, Yang ^{[1
]}

Zhang, Ying-Ying ^{[1
]}

Zhang, Xing-Hong ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Polymer Sci & Engn, MOE Key Lab Macromol Synth & Functionalizat, Hangzhou 310027, Zhejiang, Peoples R China

来源：

POLYMER | 2016年 / 82卷

基金：

美国国家科学基金会;

关键词：

RING-OPENING POLYMERIZATION; METAL CYANIDE COMPLEXES; AEROSOL-PARTICLE FORMATION; BINARY CATALYST SYSTEMS; PROPYLENE-OXIDE; ALTERNATING COPOLYMERIZATION; CYCLOHEXENE OXIDE; CYCLIC CARBONATE; POLY(PROPYLENE CARBONATE); ALIPHATIC POLYCARBONATE;

D O I：

10.1016/j.polymer.2015.11.011

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The alternating copolymerization of one-carbon (C1) building blocks including carbon dioxide (CO2) and its sulfur analogues of carbon disulfide (CS2) and carbonyl sulfide (COS) with epoxides afford new copolymers, namely polycarbonates and polythiocarbonates, with tailored chain structures and properties. This review mainly focuses on the recent advances in C1-involved copolymerization via heterogeneous catalysis of zinc-cobalt(III) double metal cyanide complex [ZneCo(III) DMCC] catalyst. The chemistry of zinc-hydroxyl bond of ZneCo(III) DMCC is responsible to the copolymerization of these C1 monomers with epoxides through the formation of CeO (S) bond. The syntheses of CO2-based copolymers with various topologies are also reviewed in detail. The utilization of CO2, COS and CS2 as monomers for polymer synthesis have significant contributions to the sustainable use of renewable resources. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：406 / 431

页数：26

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