Using carbon dioxide and its sulfur analogues as monomers in polymer synthesis

被引：91

作者：

Luo, Ming ^{[1
]}

Li, Yang ^{[1
]}

Zhang, Ying-Ying ^{[1
]}

Zhang, Xing-Hong ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Polymer Sci & Engn, MOE Key Lab Macromol Synth & Functionalizat, Hangzhou 310027, Zhejiang, Peoples R China

来源：

POLYMER | 2016年 / 82卷

基金：

美国国家科学基金会;

关键词：

RING-OPENING POLYMERIZATION; METAL CYANIDE COMPLEXES; AEROSOL-PARTICLE FORMATION; BINARY CATALYST SYSTEMS; PROPYLENE-OXIDE; ALTERNATING COPOLYMERIZATION; CYCLOHEXENE OXIDE; CYCLIC CARBONATE; POLY(PROPYLENE CARBONATE); ALIPHATIC POLYCARBONATE;

D O I：

10.1016/j.polymer.2015.11.011

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The alternating copolymerization of one-carbon (C1) building blocks including carbon dioxide (CO2) and its sulfur analogues of carbon disulfide (CS2) and carbonyl sulfide (COS) with epoxides afford new copolymers, namely polycarbonates and polythiocarbonates, with tailored chain structures and properties. This review mainly focuses on the recent advances in C1-involved copolymerization via heterogeneous catalysis of zinc-cobalt(III) double metal cyanide complex [ZneCo(III) DMCC] catalyst. The chemistry of zinc-hydroxyl bond of ZneCo(III) DMCC is responsible to the copolymerization of these C1 monomers with epoxides through the formation of CeO (S) bond. The syntheses of CO2-based copolymers with various topologies are also reviewed in detail. The utilization of CO2, COS and CS2 as monomers for polymer synthesis have significant contributions to the sustainable use of renewable resources. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：406 / 431

页数：26

共 254 条

[91]

Jeske R. C., 2008, ANGEW CHEM INT EDIT, V47, P6130

[92] Alternating copolymerization of Epoxides and cyclic anhydrides: An improved route to aliphatic polyesters [J].

Jeske, Ryan C. ;

DiCiccio, Angela M. ;

Coates, Geoffrey W. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (37) :11330-+

[93]

Kacholia K, 1997, CLIMATIC CHANGE, V35, P53, DOI 10.1023/A:1005372618899

[94] Hydrogen storage in the dehydrated Prussian blue analogues M3[Co(CN)6]2 (M = Mn, Fe, Co, Ni, Cu, Zn) [J].

Kaye, SS ;

Long, JR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (18) :6506-6507

[95] Catalysts for CO2/epoxide copolymerisation [J].

Kember, Michael R. ;

Buchard, Antoine ;

Williams, Charlotte K. .

CHEMICAL COMMUNICATIONS, 2011, 47 (01) :141-163

[96] Triblock copolymers from lactide and telechelic poly(cyclohexene carbonate) [J].

Kember, Michael R. ;

Copley, James ;

Buchard, Antoine ;

Williams, Charlotte K. .

POLYMER CHEMISTRY, 2012, 3 (05) :1196-1201

[97] Highly Active Dizinc Catalyst for the Copolymerization of Carbon Dioxide and Cyclohexene Oxide at One Atmosphere Pressure [J].

Kember, Michael R. ;

Knight, Paul D. ;

Reung, Palarp T. R. ;

Williams, Charlotte K. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (05) :931-933

[98] SELF-CATALYZED CARBON-DIOXIDE INCORPORATION SYSTEM - THE REACTION OF COPOLYMERS BEARING AN EPOXIDE AND A QUATERNARY AMMONIUM GROUP WITH CARBON-DIOXIDE [J].

KIHARA, N ;

ENDO, T .

MACROMOLECULES, 1994, 27 (22) :6239-6244

[99]

KIHARA N, 1992, MAKROMOL CHEM, V193, P1481

[100] SYNTHESIS AND REACTION OF POLYMERS BEARING 5-MEMBERED CYCLIC DITHIOCARBONATE GROUP [J].

KIHARA, N ;

TOCHIGI, H ;

ENDO, T .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1995, 33 (07) :1005-1010

← 5 6 7 8 9 10 11 12 13 14 →