Dielectric relaxation spectroscopy of ion-solvent interactions in formamide and N-methylformamide

被引:19
|
作者
Wurm, Bernhard [1 ]
Baar, Christian [1 ]
Buchner, Richard [1 ]
Barthel, Josef [1 ]
机构
[1] Univ Regensburg, Inst Phys & Theoret Chem, D-93040 Regensburg, Germany
关键词
ion-solvent interactions; formamide; N-methylformamide; dielectric relaxation spectroscopy;
D O I
10.1016/j.molliq.2006.03.004
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
in this contribution, which complements a previous publication on the dielectric relaxation of electrolytes in N,N-dimethylformamide (DMF) and N,N-dimethylacetamide (DMA) [Wurm B., Munsterer M., Richardi J., Buchner R., Barthel J., J. Mol. Liq. 119 (2005) 97], we explore the effect of the electrolytes Bu4NClO4, LiClO4, NaClO4, and NaCl on structure and dynamics of formamide (FA) and N-methylformamide (NMF) at 25 degrees C. (C) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:14 / 20
页数:7
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