Organometallic gold complexes of carborane. Theoretical comparative analysis of ortho, meta, and para derivatives and luminescence studies

被引：27

作者：

Crespo, Olga ^{[1
]}

Concepcion Gimeno, M. ^{[1
]}

Laguna, Antonio ^{[1
]}

Ospino, Isaura ^{[1
]}

Aullon, Gabriel ^{[2
,3
]}

Oliva, Josep M. ^{[4
]}

机构：

[1] Univ Zaragoza, Dept Quim Inorgan, Inst Ciencia Mat Aragon, CSIC, E-50009 Zaragoza, Spain

[2] Univ Barcelona, Dept Quim Inorgan, E-08028 Barcelona, Spain

[3] Univ Barcelona, Inst Quim Teor & Computac IQTCUB, E-08028 Barcelona, Spain

[4] CSIC, Inst Quim Fis Rocasolano, E-28006 Madrid, Spain

来源：

DALTON TRANSACTIONS | 2009年 / 19期

关键词：

ICOSAHEDRAL CARBORANES; CRYSTAL-STRUCTURE; SOLVOLYSIS; CHEMISTRY;

D O I：

10.1039/b820803d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and X-ray analysis of complexes [(mu-1,12-C(2)B(10)H(1)0){Au(PPh3)}(2)] and [(mu-1,2-C2B10H10){Au(PMe3)}(2)] have provided the experimental data needed to analyse two points. The first point is the use of these data to carry out a computational study with the aim of comparing the electronic structures and relative stabilities of the organometallic isomers [(mu-1,n-C2B10H10){Au(PR3)}(2)] (n = 2, 7, 12; R = Ph, Me) with those of the parent carborane clusters ortho-, meta- and para-carborane and the influence of the monophosphine substituents. The second point is focused in the influence of the steric demand of the monophosphine in the presence or not of aurophilic interactions in the ortho derivatives [(mu-1,2-C2B10H10){Au(PR3)}(2)] (R = Me, Ph). The photoluminescent behaviour of both the carboranes and the organometallic complexes is presented.

引用

页码：3807 / 3813

页数：7

共 36 条

[1] CRYSTAL-STRUCTURES OF CHLORO(TRIMETHYLPHOSPHINE)GOLD(I), CHLORO(TRI-(I)PROPYLPHOSPHINE)GOLD(2) AND BIS(TRIMETHYLPHOSPHINE)GOLD(I) CHLORIDE
ANGERMAIER, K
ZELLER, E
SCHMIDBAUR, H
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 472 (1-2) : 371 - 376
[2] [Anonymous], 2000, SADABS VERS 2 03
[3] Sulfur, tin and gold derivatives of 1-(2′-pyridyl)-ortho-carborane, 1-R-2-X-1,2-C2B10H10(R=2′-pyridyl, X = SH, SnMe3 or AuPPh3)
Batsanov, AS
Fox, MA
Hibbert, TG
Howard, JAK
Kivekäs, R
Laromaine, A
Sillanpää, R
Viñas, C
Wade, K
[J]. DALTON TRANSACTIONS, 2004, (22) : 3822 - 3828
[4] Baukova T.V., 1989, Metalloorg. Khim, V2, P1098
[5] DENSITY-FUNCTIONAL THERMOCHEMISTRY .3. THE ROLE OF EXACT EXCHANGE
BECKE, AD
[J]. JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (07) : 5648 - 5652
[6] Synthesis and luminescence spectroscopy of a series of [η5-CpFe(CO)2] complexes containing 1,12-dicarba-closo-dodecaboranyl and -ylene ligands
Bitner, TW
Wedge, TJ
Hawthorne, MF
Zink, JI
[J]. INORGANIC CHEMISTRY, 2001, 40 (21) : 5428 - 5433
[7] Synthesis of the first organometallic gold(I) derivatives of m-carborane: Crystal structure of [Au-2(mu-1,7-C2B10H10)(PPh3)(2)]center dot 1/2CH(2)Cl(2)
Crespo, O
Gimeno, MC
Jones, PG
Laguna, A
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 531 (1-2) : 87 - 90
[8] Organometallic gold derivatives with the [1-SitBuMe2-1,2-C2B10H10]-carboranyl ligand.: Crystal structure of [1-{Au(PPh3)}-2-SitBuMe2-1,2-C2B10H10]
Crespo, O
Gimeno, MC
Laguna, A
Peña, AM
[J]. POLYHEDRON, 1998, 17 (23-24) : 4163 - 4167
[9] Electronic effects of icosahedral carboranes.: Retentive solvolysis of (1,2-dicarba-closo-dodecaboran-1-yl)benzyl p-toluenesulfonates
Endo, Y
Sawabe, T
Taoda, Y
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (01) : 180 - 181
[10] Electronic effects of icosahedral carboranes:: kinetic evidence for interaction between boron atom and nucleophile in the solvolysis of (o-carboranyl)benzyl tosylates
Endo, Y
Taoda, Y
[J]. TETRAHEDRON LETTERS, 2001, 42 (36) : 6327 - 6331

← 1 2 3 4 →