Proton-Catalyzed Oxo-Alkene Coupling: 2-Platinaoxetane Formation

被引：16
|
作者：
Weliange, Nandita M. [1 ]
Szuromi, Endre [1 ]
Sharp, Paul R. [1 ]
机构：
[1] Univ Missouri, Columbia, MO 65211 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 25期
关键词：
H BOND ACTIVATION; OXIDATION; PLATINAOXETANES; ELIMINATION; EPOXIDATION; MECHANISM;
D O I：
10.1021/ja902180k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Formation of 2-platinaoxetane 2 from oxo complex 1 and norbornene (NB) is mediated by hydroxo complex 5. The facile reaction of 5 with NB to give protonated 2-platinaoxetane 7 supports the involvement of such reactions in Wacker alkene oxidation.
引用
收藏
页码：8736 / +
页数：3
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