Proton-Catalyzed Oxo-Alkene Coupling: 2-Platinaoxetane Formation

被引：16

作者：

Weliange, Nandita M. ^{[1
]}

Szuromi, Endre ^{[1
]}

Sharp, Paul R. ^{[1
]}

机构：

[1] Univ Missouri, Columbia, MO 65211 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 25期

关键词：

H BOND ACTIVATION; OXIDATION; PLATINAOXETANES; ELIMINATION; EPOXIDATION; MECHANISM;

D O I：

10.1021/ja902180k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Formation of 2-platinaoxetane 2 from oxo complex 1 and norbornene (NB) is mediated by hydroxo complex 5. The facile reaction of 5 with NB to give protonated 2-platinaoxetane 7 supports the involvement of such reactions in Wacker alkene oxidation.

引用

页码：8736 / +

页数：3

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