Molecular rotational diffusion detected by differential fluorescence energy

被引:4
|
作者
Torga, JR
Marconi, MC
Negri, RM
Aramendía, PF
机构
[1] Univ Buenos Aires, Fac Ciencias Exactas & Nat, Dept Fis, Lab Elect Cuant, RA-1428 Buenos Aires, DF, Argentina
[2] Univ Buenos Aires, Fac Ciencias Exactas & Nat, Dept Quim Inorgan Analit & Quim, INQUIMAE, RA-1428 Buenos Aires, DF, Argentina
关键词
D O I
10.1016/S0301-0104(99)00398-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this paper, we present a complete study of the influence of the molecular rotational diffusion movement in the fluorescence signal when a sample is excited by two short pulses, The study includes the calculations of this effect for ellipsoidal molecules, Experimental results are presented that show a fluorescence behavior influenced by the molecular rotational diffusion movement with temporal characteristics that agree with our calculations. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:249 / 257
页数:9
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