Ionic rectification properties of a bipolar interface consisting of a cationic surfactant and cation-exchange membrane

被引：9
|
作者：
Suendo, V [1 ]
Eto, R [1 ]
Tanioka, A [1 ]
机构：
[1] Tokyo Inst Technol, Dept Organ & Polymer Mat, Meguro Ku, Tokyo 152, Japan
来源：
JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2002年 / 250卷 / 02期
关键词：
bipolar interface; total rectification; cationic surfactant; cation-exchange membrane; bipolar membrane;
D O I：
10.1006/jcis.2002.8343
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A novel bipolar interface that consists of cationic surfactant and cation-exchange membrane was successfully prepared in an aqueous electrolyte system. This bipolar interface shows a ionic rectification behavior similar to that observed in bipolar membranes. However, different from bipolar membranes, this system has a total rectification behavior, where we cannot observe the occurrence of a water-splitting phenomenon, which always occurs in the bipolar membrane process under reverse bias conditions. (C) 2002 Elsevier Science (USA).
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页码：507 / 509
页数：3
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