Corrosion inhibition of mild steel in acidic media by [BMIm]Br Ionic liquid

被引:128
作者
Ashassi-Sorkhabi, H. [1 ]
Es'haghi, M. [1 ]
机构
[1] Univ Tabriz, Fac Chem, Ctr Excellence New Mat & Clean Chem, Dept Phys Chem,Electrochem Res Lab, Tabriz 5166614766, Iran
关键词
Corrosion inhibitor; Electrochemical techniques; Adsorption; HYDROCHLORIC-ACID; HCL SOLUTION; DERIVATIVES; ADSORPTION; SURFACTANTS; MECHANISM; ALLOYS;
D O I
10.1016/j.matchemphys.2008.09.019
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The inhibiting behavior of 1-butyl-3-methytimidazolium bromide [BMIM]Br on mild steel corrosion in 1.0 M HCl as corroding solution at 25 degrees C was evaluated by various corrosion monitoring techniques. The obtained results showed that [BMIM]Br is a good inhibitor for mild steel in 1.0 M HCl solution. Potentiodynamic polarization data indicated that the [BMIM]Br acts essentially as a mixed-type inhibitor. The effect of inhibitor concentration on zero charge potential (ZCP) of the mild steel in 1.0 M HCl was studied and its comparison with OCP has been made for evaluation of the mechanism of adsorption of [BMIm](+) cation. The effect of temperature on corrosion behavior of mild steel in 1.0 M HCl with addition of [BMIM]Br was studied in the temperature range of 25-45 degrees C. The inhibition efficiency decreases with the rise of temperature. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:267 / 271
页数:5
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